I checked out your analysis, and there are several minor issues with it.
Firstly, your measuerments are off by a frame or two for some of the segments. For some endings (esp. flag pole endings), you count a frame too many, and for NTSC 1-1 seg 2 you counted 2 frame too few (just because the inputs stop doesn't mean the playable time stops).
This may seem irrelevant if you counted them wrong consistently, but it's not because PAL frames and NTSC frames have different lengths, so counting a frame extra for each adds more time to PAL than NTSC.
I've made a copy of your spreadsheet with the corrected times, highlighting the changes:
https://docs.google.com/spreadsheets/d/1Ov8yMWwzbS0P0UShMPe6tH84E0tNgYOxgh-zGpoXHJc/edit?usp=sharing
Secondly, your conversion from frames to seconds for PAL used a constant that was slightly off (not only because of rounding). I decided I had enough of rounding discussions, so I replaced them with the exact fractions so the values are guaranteed to be accurate (Well, in theory, not dealing with the messiness of the real world). The spreadsheet still shows them as a rounded decimal, but if you want to get really exact you could calculate the exact difference (as a fraction) between NTSC and PAL.
Thirdly and probably most problematically, the IGT runs you were basing the measurements off are blatantly suboptimal. For example, the PAL 1-1 seg 1 loses 2 frames right away. Also, in NTSC 8-1 and PAL 8-3 you started playing a frame late, losing a frame standing and doing nothing. I noted in the spreadsheet where I for sure know you could save frames, based on existing TASes. There are more spots where I strongly suspect you could save more frames, but I didn't note them to avoid spreading false information.
That said, I don't expect these issues to change the overall conclusion. I could try to create more optimized IGT runs to get more precise numbers if people are interested, but I don't think they'll provide any significant new insights.
As a side note, I don't understand your exclusion of the 1-1 pipes as an alternative calculation. What purpose does it serve? Why not exclude the 8-4 pipes as well then?